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Typically this would be handled by an ETF, but the market for ETFs here in Australia is rather immature at the moment. It will come in time.
Pros would be exposure to a sector you think is going to outperform the wider market over your investment timeframe.
Cons will be lower diversification than the overall market - thus potentially higher volatility.
Specifically for resources - if you consider just how much weight shares like BHP and RIO have in the index, any sector specific index which contains them will be very top-heavy I'd think (ie lots and lots of exposure to those stocks - relatively little to the others)
This is a general comment only and does not constitute advice. Before making financial decisions you should seek advice from a professional adviser, who can take into account your specific circumstances and investment goals.